CHARACTERIZATION OF HEAVY METALS ATMOSPHERIC DEPOSITION FOR ASSESSMENT OF URBAN ENVIRONMENTAL QUALITY IN THE BOLOGNA CITY (ITALY)
DOI:
https://doi.org/10.6092/issn.2281-4485/3834Keywords:
air quality, leaf-washing water, moss, soil, pollution load index, incinerator plant, enrichment factorAbstract
The suburban area of Bologna city in southeast portion of Po Valley (Northern Italy) is characterized by high emission from industrial, urban, agriculture and traffic sources. The presence of an urban waste incinerator get inhabitants to require answers about impact of its emissions on the environmental quality related to human health. The concentrations of some pollutants (Ba, Cd, Co, Cr, Cu, Ni, Pb, V and Zn) were determined in topsoil, plants and mosses tissues sampled in sites selected according to different falling out conditions, due to the incinerator and other sources of atmospheric emissions that affect the monitoring area. No correlation was found between metal content and the distance of the incinerator plant. The pollution load index (PLI) calculated for soil and moss indicated a low environmental pollution, while highest values in sites downwind of incinerator and in craft area indicate a moderate pollution.
References
ADAMO P., DUDKA S., WILSON M.J., MCHARDY W.J. (2002) Distribution of trace elements in soils from the Sudberry smelting area (Ontario, Canada). Water Air & Soil Pollution 137:95-116.
ALLOWAY B.J. (1999). Atmospheric deposition of heavy metals onto agricultural land in England and Wales. In: W.W. Wenzel, D.C .Adriano, B.J. Alloway (Eds), Fifth International Conference on the Biogeochemistry of trace elements(pp. 414-415) Vienna, Austria.
ANGULO E. (1996) The Tomlinson Pollution Load Index applied to heavy metal, “Mussel-Watch” data: a useful index to assess coastal pollution. The Science of the Total Environment 187:19-56.
AZIMI S., LUDWIG A., THÉVENOT D.R., COLIN J. L. (2003) Trace metal determination in total atmospheric deposition in rural and urban areas. The Science of the Total Environment 308:247-256.
AZIMI S., ROCHER V., MULLER M., MOILLERON R., THEVENOT D.R. (2005) Sources distribution and variability of hydrocarbons and metals in atmospheric deposition in an urban area (Paris, France). The Science of the Total Environment 337: 223-239.
BERG T., STEINNES E. (1997) Use of mosses (Hylocomium splendens and Pleurozium Schreberi) as biomonitors of heavy metals deposition from relative to absolute deposition values. Environmental Pollution 98:61-71.
BERG T., RØYSET O., STEINNES E., & VADSET ,M. (1995) Atmospheric trace element deposition: principal component analysis of ICP-MS data from moss samples. Environmental Pollution 88:67-77
BERTHELSEN B.O., STEINNES E., SOLBERG W. (1995) Heavy metals concentrations in plants in relation to atmospheric heavy metal deposition. Journal of Environmental Quality 24:1018-1026.
BOAMPONSEM L.K., ADAM J.I., DAMPARE S.B., NYARKO B.J.B., ESSUMANG D.K. (2010) Assessment od atmospheric heavy metal deposition in the Tarkwa gold mining area of Ghana using ephiphytic lichens. Nuclear Instruments and Methods in Physics Research 268:1492-1501.
CAPUANO F., CAVALCHI B., MARTINELLI G., PECCHINI G., RENNA E., SCARONI I., BERTACCHI M., BIGLIARDI G. (2005) Environmental protection for PCDD/PCDF, PAH, PCB and heavy metals around the incinerator power plant of Reggio Emilia town (Northern Italy) and surrounding main roads. Chemosphere 58:1563-1569.
COLLETT R.S., ODUYEMI K., LILL D.E. (1998) An investigation of environmental concentrations of cadmium and lead in airborne matter and surface soils within the locality of a municipal waste incinerator. The Science of the Total Environment 209:157-167.
COSKUN M., CAYR A., COSKUN M., KILICO. (2011) Heavy metal deposition in moss samples from East and South Marmara Region, Turkey. Environmental Monitoring Assessment 174:219-227.
DE TEMMERMAN L., HOENIG M. (2004) Vegetable crops for biomonitoring lead and cadmium deposition. Journal of Atmospheric Chemistry 49:121-135.
DONG X., LI C., LI J., WANG J., LIU S., YE B. (2010) A novel approach for soil contamination assessment from heavy metal pollution: A linkage between discharge and adsorption. Journal of Hazardous Materials 175:1022-1030.
DRAGOVIĆ S., MIHAILOVIĆ N. (2009) Analysis of mosses and topsoils for detecting sources of heavy metal pollution: multivariate and enrichment factor analysis. Environmental Monitoring Assessment 157:383-390
EUROPEAN ENVIRONMENT AGENCY, 2008. COPERT (Computer Program to calculate Emission from Roads Traffic).
FAUS-KESSLER T., DIETL C., TRITSCHLER J., PEICHLL. (1999) Temporal and spatial trends of metal contents of Bavaria mosses Hypnum cupressiforme. The Science of the Total Environment 232:13-25.
FAUS-KESSLER T., DIETL C., TRITSCHLER J., & PEICHL L. (2000) Correlation patterns of metals in the epiphytic moss Hypnum cupressiforme in Bavaria. Atmospheric Environment 35:427-439.
FERNÁNDEZ A.J., CARBALLEIRA A.A. (2001) A comparison of indigenous mosses and topsoils for use in monitoring atmospheric heavy metal deposition in Galicia (North-West Spain). Environmental Pollution 114:431-441.
FERNÁNDEZ J.A., EDERRA A., NÚÑEZ E., MARTÍNEZ-ABAIGAR J., INFANTE M., HERAS P., ELÍAS M.J., MAAMDAKA V., CARBAILLERA A.A. (2002) Biomonitoring of metal deposition in northern Spain by moss analysis. The Science of the Total Environment 300:115-127.
FERNÁNDEZ A.J., TERNERO, M., BARRAGÁN, F.J., & JIMÉNEZ, J.C. (2000) An approach to characterization of sources of urban airborne particles through heavy metal speciation. Chemosphere-Global Change Science 2:123-126.
FERNÁNDEZ ESPINOSA A.J., ROSSINI-OLIVA S. (2006) The composition and relationships between trace element levels in inhalable atmospheric particles (PM10) and in leaves of Nerium oleander L. and Lantana camera L. Chemosphere 62:1665-1672.
FIGUEIRA R., SÉRGIO C., SOUSA A.J. (2002) Distribution of trace metals in moss biomonitoring and assessment of contamination sources in Portugal. Environmetal Pollution 118:153-163.
FUJIWARA F., REBAGLIATI R.J., DAWIDOWSKI L., GÓMEZ D., POLLA G., PEREYRA V., SMICHOWSKI P. (2011) Spatial and chemical patterns of size fractionated road dust collected in a megacity. Atmospheric Environment 45:1497-1505.
FRANZARING J., HÖGYP., ERB S., FRANGMAIER A. (2010) Responses of canoly and soil climate in a six year free-air CO2 enrichment study with spring crops. Agricultural and Forest Meteorology 150:354-360.
GALAN E., GONZÁLES I., FERNÁNDEZ-CALIANI J.C. (2008) Residual pollution load of soils impacted by the Aznalcóllar (Spain) mining spill after clean-up operations. The Science of the Total Environment 286:167-179.
GERDOL R., BRAGAZZA L., MARCHESINI R., ALBER R., BONETTI L., LORENZONI G., ACHILLI M., BUFFONI A., DE MARCO N., FRANCHI M., PISON S., GIAQUINTA S., PALMIERI F., SPEZZANO P. (2000) Monitoring of heavy metal deposition in Northen Italy by moss analysis. Environmental Pollution 108:201-208.
GIORDANO S., ADAMO P., MONACI F., PITTAO E., TRETIACH M., BARGAGLI R. (2009) Bags with oven-dried moss for the active monitoring of airborne trace elements in urban areas. Environmental Pollution 157:2798-2805.
GONZÁLEZ-MIQUEO L., ELUSTONDO D., LASHERAS E., BERMEJO R., SANTAMARÍA J.M. (2010) Heavy metal and nitrogen monitoring using moss and top soil samples in a Pyrenean Forest catchment. Water Air & Soil Pollution 210:335-346.
GOODMAN G.T., ROBERTS T.M. (1971) Plants and soil as indicators of metals in the air. Nature 231:267-272.
GRAY C.W., MCLAREN R.G., ROBERTS A.H.C. (2003) Atmospheric accessions of heavy metals to some New Zealand pastoral soils. The Science of the Total Environment, 305, 105-115.
HUTTON M., WADGE A., MILLIGAN P.J. (1988) Environmental levels of cadmium and lead in the vicinity of a major refuse incinerator. Atmospheric Environment 22:411-416.
JAN F.A,, ISHAQ M., INSANULLAN I., ASIM S.M. (2010) Multivariate statistical analysis of heavy metals pollution in industrial area and its comparison with relatively less polluted area: A case study from the City of Peshawar and district Dir Lower. Journal of Hazardous Material 176:609-616.
LI C., KANG S., ZHANG Q. (2009) Elemental composition of Tibetan Plateau top soils and its effect on evaluating atmospheric pollution transport. Environmental pollution 157:2261-2265.
LLOBET J.M., SCHUHMACHER M., DOMINGO J.L. (2002) Spatial distribution and temporal variation of metals in the vicinity of a municipal solid waste incinerator after a modernization of the flue gas cleaning system of the facility. The Science of the Total Environment 284:205-214.
MADRID L., DIAZ-BARRIENTOS E., MADRID F. (2002) Distribution of heavy metal contents in urban soils in parks of Seville. Chemosphere 49:1301-1308.
MANTOVI P., BONAZZI G., MAESTRI E., MARMIROLI N. (2003) Accumulation of copper and zinc from liquid manure in agricultural soils and crop plants. Plant & Soil 250:249-257.
MENESES M., LLOBET J.M., GRANERO S., SHUHMACHER M., DOMINGO J.L. (1999) Monitoring metals in the vicinity of a municipal waste incinerator: temporal variation in soil and vegetation. The Science of the Total Environment 226:157-164.
MINGORANCE M.D., VALDÉS B., ROSSINI OLIVA S. (2007) Strategies of heavy metal uptake by plants growing under industrial emission. Environment International 33:514-520.
MONACI F., BARBAGLI R. (1997) Barium and other trace metals as indicators of vehicle emission. Water Air & Soil Pollution 100:89-98.
MORALES M.M., MARTÍ P., LIOPIS A., CAMPOS L., SAGRADO S. (1999) An environmental study by factor analysis of surface seawater in the Gulf of Valencia (Western Mediterranean). Analytica Chimica Acta 394:109-117.
MORSELLI L., BARTOLI M., BRUSONI B., PASSARINI F. (2002) Application of an integrated environmental monitoring system to an incineration plant. The Science of the Total Environment 289:177-188.
NADAL M., SCHUHMACHER M., DOMINGO J. (2004) Metal pollution of soils and vegetation in an area with petrochemical industry. The Science of the Total Environnement 321:59-69.
NADAL M., BOCIO A., SCHUMACHERM., DOMINGO, J.L. (2005) Trends in the levels of metals in soils and vegetables samples collected near a Hazardous waste incinerator. Archives of Environmental Contamination and Toxicology 49:290-298.
NICHOLSON F.A., SMITH S.R., ALLOWAY B.J., CARLTON-SIMITH C., CHAMBERS B.J. (2003) An inventory of heavy metal input to agricultural soil in England and Wales. The Science of the Total Environment, 311:205-219.
NRIAGU J.O., PACYNA J.M. (1988) Quantitative assessment of worldwide contamination of air, water and soils by trace metals. Nature 333:134-139.
REIMANN C., HALLERAKER JO.H., KASHULINA G., BOGATYREV I. (1999) Comparison of plant and precipitation chemistry in catchments with different levels of pollution on the Kola Peninsula, Russia. The Science of the Total Environment 243:169-191.
REIMANN C., KOLLER F., FRENGSTAND B., KASHULINA G., NISKAVAARA H., ENGLMAIER P. (2001) Comparison of the elemental composition in several plant species and their substrate from 1500000-km2 area in Northern Europe. The Science of the Total Environment 278:87-112.
REIMANN C., DE CARITAT P. (2000) Intreinsic flaws of element enrichment factors (EFs) in environmenatl geochemistry. Environmental Science & Technology 34:5084-5091.
RIMMER D.L., VIZARD C.G., PLESS-MULLOLI T., SINGLETON I., AIR V.S., KEATINGE Z.A.F. (2006) Metal contamination of urban soils in the vicinity of a municipal waste incinerator: One source among many. The Science of the Total Environment 356:207-216.
RODRÍGUEZ J.A., NANOS N., GRAU J.M., GIL L., LÓPEZ-ARIAS M. (2008) Multiscale analysis of heavy metal contents in Spanish agricultural topsoils. Chemosphere 70:1085-1096.
ROSSINI-OLIVA S., MINGORANCE M.D. (2004) Study of the impact of industrial emission on the vegetation grown around Huelva (South Spain) city. Journal of Atmospheric Chemistry 49:291-302.
SCHUHMACHER M., GRANERO S., BELLÉS M., LLOBET J.M,, DOMINGO J.L. (1996) Levels of metals in soils and vegetation in the vicinity of a municipal solid waste incinerator. Toxicological & Environmental Chemistry 56:119-132.
SCHUHMACHER M., MENESES M., GRANERO S., LLOBERT J.M., DOMINGO J.L. (1997) Trace element pollution in soils collected near a municipal solid waste incinerator. Bulletin of Environmental Contamination and Toxicology 59:861-867.
SUTHERLAND R.A. (2000) Bed sediment-associated trace metals in an urban stream, Oahu, Hawai. Environmental Geology 39:611-627.
SUTHERLAND R.A., TOLOSA C.A. (2000) Multi- element analysis of road-deposited sediment in an urban drainage basin, Honolulu, Hawaii. Environmental Pollution 110:483-485.
TASK FORCE ON HEAVY METALS (2006) Sufficiency and effectiveness review of the 1998 protocol on heavy metals, UN/ECE convention on long range transboundary air pollution.
VALERIO F., PICCARDO M.T., LAZZAROTTO A., BALDUCCI D., BESCIANINI C. (1995) Exposure to airborne cadmium in some Italian urban areas. The Science of the Total Environnent 172,57-63.
VIANNA N.A., GONÇALVES D., BRANDÃO F., DE BARROS R.P., FILHO G.M.A., MEIRE R.O., TORRES, J.P.M., MALM O., JÙNIOR A.D., ANDRADE L.R. (2011) Assessment of heavy metals in the particulate matter of two Brazilian metropolitan areas by using Tillandsia usneoides as atmospheric biomonitor. Environmental Science and Pollution Research 18:416-427.
VOGG H., BRAUN H., METZEGER M., SCHNEIDER J. (1986) The specific role of cadmium and mercury in municipal solid waste incineration. Waste Management Research 4:65-74.
VOUTSA D., SAMARA C. (1998) Dietary intake of trace elements and polycyclic aromatic hydrocarbons via vegetable grown in an industrial Greek area. The Science of the Total Environment 218: 203-216.
Downloads
Published
How to Cite
Issue
Section
License
Copyright (c) 2011 Livia Vittori Antisari, Serena Carbone, Chiara Ferronato, Andrea Simoni, Gilmo Vianello
Copyrights and publishing rights of all the texts on this journal belong to the respective authors without restrictions.
Articles published since 2020 are licensed under a Creative Commons Attribution 4.0 International License:
Previous articles are licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported License: