ADSORPTION OF GLYPHOSATE AND AMPAIN AGRICULTURAL SOILS

Authors

  • Nicola Rampazzo Institute of Soil Research, Department of Forest and Soil Sciences, University of Natural Resources and Life Sciences, Vienna
  • Gorana Rampazzo Todorovic Institute of Soil Research, Department of Forest and Soil Sciences, University of Natural Resources and Life Sciences, Vienna
  • Axel Mentler Institute of Soil Research, Department of Forest and Soil Sciences, University of Natural Resources and Life Sciences, Vienna

DOI:

https://doi.org/10.6092/issn.2281-4485/3928

Keywords:

adsorption, glyphosate, AMPA, soils

Abstract

Immediately after application glyphosate is mostly adsorbed in the upper 2 cm of soils, and is then transported and adsorbed after few days in deeper soil horizons with concomitant increasing content of its metabolite aminomethylphosphonic acid (AMPA). This work confirmed previous studies, where Fe-oxides seem to play a major role in the adsorption of glyphosate and AMPA in soils:  the Chernozem featured lower contents of Fed and Feo, with consequently lower adsorption of glyphosate and AMPAas compared with the higher weathered Cambisol and Stagnosol.

References

BARJA B.C., HERSZAGE, J., DOS SANTOS AFONSO, M. (2001) Iron(III)- phosphonate complexes. Polyhedron 20:1821-1830.

CANDELA L., ÁLVAREZ-BENEDI J., CONDESSO DE MELO M.T., RAO P.S. C. (2007) Laboratory studies on glyphosate transport in soils of the Maresme area near Barcelona, Spain: Transport model parameter estimation. Geoderma 140:8-16.

GHANEM A., BADOS P., ESTAUN A.R., DE ALENCASTRO L.F., TAIBI S., EINHORN

J., AND MOUGIN C. (2007) Concentrations and specific loads of glyphosate, diuron, atra-zin, nonylphenol and metabolites thereof in French urban sewage sludge. Chemosphere 69:1368-1373.

GIMSING A.L., BORGGAARD O.K., JACOBSEN O.S., AAMAND J., SØRENSEN J. (2004) Chemical and microbiological soil characteristics controlling glyphosate mineraliza-

tion in Danish surface soils. Appl. Soil Ecol. 27:233-242.

HASLMAYR H. P. (2010) “Rote Liste” schützenswerter Böden Österreichs: Eine

Methode zur Definition von schützenswerten Bodenformen als Planungsgrundlage flä-chenwirksamer Landnutzungen. Dissertation, Universität für Bodenkultur Wien.

LANDRY D., DOUSSET S., FOURNIER J.-C., ANDREUX F. (2005) Leaching of glyphosate and AMPA under two soil management practices in Burgundy vineyards (Vos-ne-Romanée, 21-France). Environ. Pollut. 138:191-200.

LOCKE M.A., ZABLOTOWICZ R.M. (2004) Pesticides in Soil – Benefits and

limitations to Soil Health. Managin Soil Quality: Challenges in Modern Agriculture. Eds Schjønning, Elmholt S and Christensen BT. CAB International 239-260.

MAMY L., BARRIUSO E., GABRIELLE B. (2005) Environmental fate of herbicides tri-fularin, metazachlor, metamitron and sulcotrione compared with that of glyphosate, a sub-stitute broad spectrum herbicide for different glyphosate-resistant crops. Pest. Manag. Sci. 61, 905-916.

MENTLER A., PAREDES M., FUERHACKER M. (2007) Adsorption of glyphosate to cambisols, podzols and silica sand. Alfa conference proceedings, Salzburg.

MORILLO E., UNDABEYTIA T., MAQUEDA C., RAMOS A. (2000) Glyphosate ad-sorption on soil of different characteristics: Influence of copper addition. Chemosphere 40:103-107.

NESTROY O., DANNEBERG O.H., ENGLISCH M., GEßL A., HAGER H., HERZBERGER E., KILIAN W., NELHIEBEL P., PECINA E., PEHAMBERGER A., SCHNEIDER W., WAGNER J. (2000) Systematische Gliederung der Böden Österreichs (Österreichische Bodensystematik 2000). Mitt. der ÖBG, Heft 60, Wien.

PERUZZO P.J., PORTA A.A., RONCO A.E. (2008) Levels of glyphosate in surface waters, sediments and soils associated with direct sowing soybean cultivation in north pampasic region of Argentina. Environ. Pollut. DOI: 10.1016/j.envpol.2008.01.015

PESSAGNO R.C., TORRES SÁNCHEZ R.M, DOS SANTOS AFONSO M. (2008) Glyphosate behavior at soil and mineral-water interferences. Environ. Pollut. 153(1):53-59.

RAMPAZZO TODOROVIC G., MENTLER A., POPP M., HANN S., KÖLLENSPERGER G., RAMPAZZO N., BLUM W.E.H. (2012) Determination of glyphosate and AMPA in three representative agricultural Austrian soils with a HPLC-MS/MS method.- Soil & Sediment. Accepted

RAMPAZZO TODOROVIC G., MENTLER A., RAMPAZZO N., BLUM W.E.H., EDER A., STRAUSS P. (2010) Dispersion of Glyphosate in soil through erosion. EQA 4 :15-28, DOI : 10.6092/issn2281-4485/3800.

SCHNURER Y., PERSSON P., NILSSON M., NORDGREN A., GIESLER R. (2006) Effects of surface sorption on microbial degradation of glyphosate. Environ. Sci. Technol. 40: 4145-4150.

SØRENSEN S.R., SCHULTZ A., JACOBSEN O.S., AAMAND J. (2006) Sorption, desorption and mineralisation of the herbicides glyphosate and MPCA in samples from two Danish soil and subsurface profiles. Environmental Pollution 141:184-194.

SOULAS G., LAGACHERIE B. (2001) Modelling of microbial degradation of pesticides in soils. Biol. Fertil. Soils 33:551-557.

WRB (2006) World reference base for soil resources 2006. World Soil Resources Reports, No.103. FAO, Rome.

ZHOU D.M., WANG Y.J., CANG L., HAO X. Z., LUO X.S. (2004) Adsorption and co-sorption of cadmium and glyphosate on two soils with different characteristics. Chem. 57:1237-1244.

Downloads

Published

2013-09-25

How to Cite

Rampazzo, N., Rampazzo Todorovic, G., & Mentler, A. (2013). ADSORPTION OF GLYPHOSATE AND AMPAIN AGRICULTURAL SOILS. EQA - International Journal of Environmental Quality, 10(10), 1–10. https://doi.org/10.6092/issn.2281-4485/3928

Issue

Vol. 10 (2013)

Section

Articles

License

Copyright (c) 2013 Nicola Rampazzo, Gorana Rampazzo Todorovic, Axel Mentler

Copyrights and publishing rights of all the texts on this journal belong to the respective authors without restrictions.

Articles published since 2020 are licensed under a Creative Commons Attribution 4.0 International License:

Creative Commons License

 

Previous articles are licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported License:

Creative Commons License